Additionsverbindungen von Methylhalogensiianen und Pyridin bei tiefen Temperaturen/ Addition Compounds of Methylhalogenosilanes and Pyridine at Low Temperatures
Open Access
- 1 September 1982
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 37 (9) , 1174-1177
- https://doi.org/10.1515/znb-1982-0915
Abstract
By analyzing the melting point diagrams of some methylhalogenosilane-pyridine systems the existance of the stable addition compounds CH3SiCl3 · 2 py, CH3SiBr3 · 2 py, (CH3)2SiBr2 · py, (CH3)3SiBr · py was proved. In the systems (CH3)2SiCl2/py and (CH3)2SiBr2/py unstable 1:2-complexes are also found. (CH3)3SiCl forms no complexes with pyridine.Keywords
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