Chiral Cyclopentadienes
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (11) , 814-817
- https://doi.org/10.1055/s-1989-27399
Abstract
Efficient syntheses of enantiomerically pure cyclopentadienes which undergo stereoselective and regioselective high pressure cycloadditions with nonsymmetric dienophiles are reported. As these compounds show a quite high chemical as well as thermal stability they are useful as templates in the generation of pure enantiomers by diastereoselective adduct transformation and subsequent retro-Diels-Alder reaction.Keywords
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