Pair-Wise Interactions by Gas Chromatography; Part III:1,2Synthesis of Isosteric Stationary Phases for Gas Chromatography
- 1 January 1993
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1993 (09) , 909-919
- https://doi.org/10.1055/s-1993-25968
Abstract
Retention in gas/liquid partition chromatography depends on the size and, to a lesser extent, on the form of the solvent used as stationary phase. How the measurement of interaction free enthalpies between a functional group and a solute free of size and form effects synthesis and properties of seven high molecular weight solvents is described. The monofunctional paraffin derivatives have the same form and nearly the same molar volume as that of their parent alkane 19,24-dioctadecyldotetracontane.Keywords
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