Alcoxy-2, aryloxy-2, acyloxy-2 cyclohexanones. Synthèse et étude de leur équilibre conformationnel
- 1 September 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (17) , 2759-2766
- https://doi.org/10.1139/v76-390
Abstract
We show a linear Hammett correlation in the conformational equilibrium of 2-aryloxycyclohexanones when the X substituent located para on the phenyl ring is electron withdrawing. This leads to the prediction of the equatorial position of the substituent in the 2-acyloxycyclohexanones. The conformational equilibria of 2-alcoxycyclohexanones (R = CH3 to C(CH3)3) also are examined.Keywords
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