Study of the water-bentonite system by vapour adsorption, immersion calorimetry and X-ray techniques: I. Micropore volumes and internal surface areas, following Dubinin's theory
- 1 March 1987
- journal article
- Published by Mineralogical Society in Clay Minerals
- Vol. 22 (1) , 1-9
- https://doi.org/10.1180/claymin.1987.022.1.01
Abstract
The adsorption and desorption of water, the layer spacing of the montmorillonite with increasing water content and the heat of immersion with water have been measured for a Na-bentonite and two Ca-bentonites. The bentonite-water system is treated in terms of a micropore-filling process. Uptake of water occurs in discrete stages as the montmorillonite structure expands and the internal surface is calculated from these discrete stages of water adsorption.Keywords
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