An exceptionally ready interconversion of configurational isomers in atisine
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 644-645
- https://doi.org/10.1039/c29700000644
Abstract
Atisine in solution is shown to contain a 2:1 mixture of two isomeric species whose rate of interconversion is fast on the n.m.r. time scale in polar hydrogen-bonding solvents, but relatively slow in solvents which would not stabilize an ionic species, leading to the suggestion that it is a mixture of configurational isomers interconvertible via a zwitterion.Keywords
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