THE EMISSION SPECTRUM OF THE CCI RADICAL

1 February 1961

journal article
Published by Canadian Science Publishing in Canadian Journal of Physics

Vol. 39 (2) , 252-262
https://doi.org/10.1139/p61-025

Abstract

A rotational analysis of the 2780 Å emission band obtained in a microwave discharge through CCl₄ vapor and photographed on a 20-ft grating spectrograph shows that a ²Δ_i(b) → ²Π_r(a) transition of the CCl radical is responsible, not ²Σ → ²Π(a) as reported by previous workers. Molecular constants are given for the combining states, as well as a vibrational analysis that identifies the 2780 Å band as the (0–0) band.

Keywords

SPECTRUM

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