A New Synthesis of (±)-Celacinnine by Means of Non-spermoidine-based Methodology
- 1 January 1985
- journal article
- research article
- Published by CLOCKSS Archive in HETEROCYCLES
- Vol. 23 (10) , 2525-2529
- https://doi.org/10.3987/r-1985-10-2525
Abstract
(.+-.)-Celacinnine was synthesized relaying on the novel methodology which features nucleophilic ring opening of 2-substituted 5,6-dihydro-4H-1,3-oxazine as a carboxamide synthon and requires neither spermidine nor amino acid condensation process for the lactam framework.Keywords
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- Total synthesis of (.+-.)-celacinnine, (.+-.)-celallocinnine, (.+-.)-celafurine, and (.+-.)-celabenzineJournal of the American Chemical Society, 1981
- Macrocyclic spermidine alkaloids from Maytenus serrata and Tripterygium wilfordiiThe Journal of Organic Chemistry, 1977