THE CONFIGURATION OF DEOXYSTREPTAMINE
- 1 April 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (4) , 858-862
- https://doi.org/10.1139/v63-123
Abstract
The nuclear magnetic resonance (n.m.r.) spectrum of 5-O-methyl-l,3-di-N-methyl-4,6-di-O-acetyldeoxystreptamine dihydrogenperchlorate requires the all-trans configuration since the signal for the equivalent ring hydrogens at the 4- and 6-positions is in the form of a triplet with a spacing of 10 c.p.s. This spacing requires these hydrogens to be axial and coupled with axial hydrogens at the neighboring 1-, 3-, and 5-positions.Keywords
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