Thermodynamic behaviour of aqueous solutions of cyclic ethers. Part 1.—Enthalpies and volumes of mixing
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 66, 1073-1080
- https://doi.org/10.1039/tf9706601073
Abstract
The excess enthalpies HE for mixtures of water with 1,4-dioxan, 1,3-dioxan and trimethylene oxide (oxetane), and the excess volumes of mixing VE for the same systems together with water + tetrahydrofuran have been measured as a function of composition and temperature. In most cases, measurements were made at 5, 25 and 45°C but for 1,4-dioxan (m.p. 11°C) measurements were made at 15°C. The results are discussed in the light of current ideas concerning aqueous solutions.Keywords
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