Second-Order Interactions between Polar Molecules
- 15 December 1966
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 45 (12) , 4664-4666
- https://doi.org/10.1063/1.1727551
Abstract
The interaction energy between polar molecules is calculated up to second-order perturbation contributions. The essential result is that the dipole—induced-dipole energy calculated by quantum theory differs considerably from the corresponding classical expression. This is confirmed by a variational calculation.Keywords
This publication has 2 references indexed in Scilit:
- Theory of long-range dispersion forcesDiscussions of the Faraday Society, 1965
- Intermolecular Forces and Equation of State of GasesAdvances in Chemical Physics, 1957