Some reactions of pentafluorothiophenol. Preparation of some pentafluoro-phenylthio metal derivatives
- 15 August 1968
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 46 (16) , 2699-2706
- https://doi.org/10.1139/v68-444
Abstract
The new compounds M(SC6F5), where M = Cs, Tl, Cu, Au, and Ph3Pb; M(SC6F5)2, where M = Pb, Cd, Hg, Ni, and Pt; M(SC6F5)3, where M = As or Bi; and Sn(SC6F5)4 have been prepared from pentafluorothiophenol and metal ions in aqueous solution. Zn(SC6F5)2 has been prepared from zinc oxide and pentafluorothiophenol in methanol. The compounds have been characterized, and their infrared spectra and 1H and 19F nuclear magnetic resonance spectra examined.Some of the reducing properties of pentafluorothiophenol and its polymerization have been studied.Keywords
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