Selective complexation of disaccharides by a novel D 2-symmetrical receptor in protic solvent mixtures
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1493-1494
- https://doi.org/10.1039/cc9960001493
Abstract
The synthesis of an optically active, 1,1′-binaphtyl-derived cyclophane receptor with a preorganized central cavity lined with four anionic phosphodiester groups for ionic hydrogen bonding is described. In competitive protic solvent mixtures, this receptor forms stable 1:1 complexes with disaccharides whereas the smaller monosaccharides are not significantly bound.Keywords
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