Innovation in a chemical reaction process using a supercritical water microreaction system: environmentally friendly production of ε-caprolactam
- 2 September 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 2208-2209
- https://doi.org/10.1039/b206539h
Abstract
Our microreaction system using supercritical water solutions achieves nearly 100% yield and 100% selectivity for ε-caprolactam production at reaction times shorter than 1 s.Keywords
This publication has 9 references indexed in Scilit:
- The development of new heterogeneous catalytic processes for the production of ε-caprolactamApplied Catalysis A: General, 2001
- Non-catalytic and selective alkylation of phenol with propan-2-ol in supercritical waterChemical Communications, 2001
- Noncatalytic Organic Synthesis Using Supercritical Water: The Peculiarity Near the Critical PointAngewandte Chemie International Edition in English, 1999
- Noncatalytic Beckmann Rearrangement of Cyclohexanone-Oxime in Supercritical WaterThe Journal of Organic Chemistry, 1998
- An in situ Raman spectroscopy study of subcritical and supercritical water: The peculiarity of hydrogen bonding near the critical pointThe Journal of Chemical Physics, 1998
- Applications of High-Temperature Aqueous Media for Synthetic Organic ReactionsThe Journal of Organic Chemistry, 1997
- Spectroscopic Measurement of pH in Aqueous Sulfuric Acid and Ammonia from Sub- to Supercritical ConditionsIndustrial & Engineering Chemistry Research, 1996
- Factors affecting selectivity in the rearrangement of cyclohexanone oxime to caprolactam over modified aluminasApplied Catalysis A: General, 1992
- Ion product of water substance, 0–1000 °C, 1–10,000 bars New International Formulation and its backgroundJournal of Physical and Chemical Reference Data, 1981