Synthesis of β-(diphenylphosphinoyl) ketones

1 January 1983

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1

p. 2879-2891
https://doi.org/10.1039/p19830002879

Abstract

The title compounds may be made by addition of phosphorus nucleophiles (Ph₂PO^–, Ph₂POMgX, Ph₂PCl) to enones, by addition of phosphorus-stabilised carbanions to α-carbonyl cation equivalents (2,3-dichloropropene, epoxides, and α-MeO-ketones) and by oxidation of allyl diphenylphosphine oxides.

Keywords

DIPHENYLPHOSPHINOYL
KETONES
TITLE
NUCLEOPHILES
DIPHENYLPHOSPHINE
DICHLOROPROPENE
MADE
PH2PCL
CARBONYL

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