An unusual mass spectral fragmentation of C-4 alkylated cholesterols
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 537b-538
- https://doi.org/10.1039/c3974000537b
Abstract
The mass spectra of C-4-alkylated cholest-5-en-3β-hydroxysterols are characterized by an ion (m/e 331) resulting from the unusual intramolecular transfer of the 3β-hydroxy-group to the charge-retaining fragment with concomitant loss of ring A.Keywords
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