New amido- and imido-titanium complexes
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 550-552
- https://doi.org/10.1039/c39830000550
Abstract
CpTiCl3(cp =η5-C5H5) in reaction with Me3SiN(H)R (R = Et, Pri, But, or Ph) yields the amido complexes cpTi(Cl)2N(H)R, which react further by HCl abstraction to give the corresponding centrosymmetric binuclear imido complexes [cp(Cl)Ti]2(µ-RN)2; substitution of the chloride ligands by organic groups is possible with the imido complexes, as is reversible reduction to stable anionic complexes.Keywords
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