Vapor-Phase Asymmetric Hydroformylation
- 1 June 2000
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 29 (6) , 694-695
- https://doi.org/10.1246/cl.2000.694
Abstract
Polystyrene-supported (R,S)-BINAPHOS–Rh complex was demonstrated to be applicable to the asymmetric hydroformylation of gaseous substrates in a non-solvent system: 3,3,3-trifluoropropene (2a) and (Z)-2-butene (2b) were converted into the corresponding branched aldehydes with 90% and 80%ee, respectively.Keywords
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