Theoretical Signal-to-noise Ratio and Resolution in Ion-cyclotron-resonance Spectroscopy
- 1 May 1982
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 55 (5) , 1425-1430
- https://doi.org/10.1246/bcsj.55.1425
Abstract
A comparison is made theoretically of the signal-to-noise (S/N) ratio between the usual slow-sweep or the continuous-wave method and the pulsed Fourier-transform (FT) method in ion-cyclotron-resonance spectroscopy. Expressions of the maximum S/N ratio, as characterized by experimental parameters, are given in concrete form for both methods. Based on these expressions, it is shown that the FT method has a Fellgett S/N advantage when the resolution of a measurement is selected so as to be nearly equal to the true linewidth. A tradeoff between the S/N ratio and the resolution is discussed, and a possible reconciliation is suggested of inconsistent statements on a relation between the S/N and the resolution in the literature.This publication has 12 references indexed in Scilit:
- Detection theory of ion cyclotron resonance phenomenaInternational Journal of Mass Spectrometry and Ion Physics, 1980
- Resolution and signal-to-noise in Fourier transform mass spectrometryAnalytical Chemistry, 1980
- Theoretical signal-to-noise ratio and mass resolution in Fourier transform ion cyclotron resonance mass spectrometryAnalytical Chemistry, 1979
- Signal modeling for ion cyclotron resonanceThe Journal of Chemical Physics, 1978
- Fourier transform methods in spectroscopyJournal of Chemical Education, 1975
- Fourier transform ion cyclotron resonance spectroscopyChemical Physics Letters, 1974
- A Trapped Ion Analyzer Cell for Ion Cyclotron Resonance SpectroscopyReview of Scientific Instruments, 1970
- Theory of Collision-Broadened Ion Cyclotron Resonance SpectraThe Journal of Chemical Physics, 1967
- Application of Fourier Transform Spectroscopy to Magnetic ResonanceReview of Scientific Instruments, 1966
- Ion Cyclotron Resonance and the Determination of Collision Cross SectionsPhysical Review B, 1963