Rotational barriers about phosphorus–nitrogen bonds
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 13,p. 713
- https://doi.org/10.1039/c29690000713
Abstract
Studies of the low-temperature n.m.r. spectra of compounds R1PCl·NR2 2, and of analogous fluorinated and P(O) compounds, suggest a pπ–dπ contribution to the PN rotational barrier.Keywords
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