The Elimination Reaction of Chlorobutane over Some Molten Salts
- 1 May 1977
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 50 (5) , 1351-1352
- https://doi.org/10.1246/bcsj.50.1351
Abstract
The elimination reactions of hydrogen chloride from 1-chlorobutane and 2-chlorobutane over molten salts (ZnCl2, SnCl2, CuCl melts) have been studied by using both a microreactor and a conventional flow reactor. The preferential formation of cis-2-butene in the reaction of 2-chlorobutane can be explained in terms of the stereochemistry of the surface-adsorbed carbonium ion.Keywords
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