Chemistry of methylinyltricobalt enneacarbonyls. Part IX. Reactions with Grignard and organolithium reagents
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 1794-1798
- https://doi.org/10.1039/dt9730001794
Abstract
Aryl Grignard reagents react with halogenomethinyltricobalt enneacarbonyls to give the corresponding aryl-clusters in good yield. Substitution with alkyl Grignard reagents is not possible. Reactions with organolithium and Grignard reagents (under a CO atmosphere) invariably give products formed by CO insertion, principally the acid, HO2CCCo3(CO)9. Possible intermediates in these reactions are discussed.Keywords
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