Preparation and crystal structure of the dinuclear, asymmetric dioxo complex (η5-C5Me5)(CO)3W–W(O)2(η5-C5Me5)
- 1 January 1987
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1795-1796
- https://doi.org/10.1039/c39870001795
Abstract
The dinuclear, asymmetric, dioxo complex (η5-C5Me5)(CO)3W–W(O)2(η5-C5Me5)(3) can be prepared by air oxidation of [(C5Me5)W(CO)2]2(1) or (C5Me5)W(CO)2(µ-H)]2(2); in this compound WI is directly connected with WV.Keywords
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