Catalytic enantioselective 1,3-dipolar cycloaddition reactions of nitrones
Top Cited Papers
- 11 July 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1449-1458
- https://doi.org/10.1039/b004597g
Abstract
The rapid developments in the field of catalytic enantioselective 1,3-dipolar cycloaddition reactions of nitrones which have occurred during the last six years are reported. A series of catalysts has been applied for both the normal electron-demand and inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones with electron-deficient and electron-rich alkenes, respectively. In several cases a high degree of control of both the diastereo- and enantioselectivity has been achieved.Keywords
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