Polarity reversal catalysis of hydrogen atom abstraction reactions
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1322-1324
- https://doi.org/10.1039/c39870001322
Abstract
Overall transfer of electron deficient hydrogen to the electrophilic t-butoxyl radical is catalysed by Me3N → BH2Hext; hydrogen atom abstraction is actually brought about by the nucleophilic Me3N → ḂHHext.Keywords
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