Synthesis and crystal structure of a complex in which a single macrocyclic ligand binds six cu II centres in a cyclohexane boat arrangement
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 488-489
- https://doi.org/10.1039/c39900000488
Abstract
The hexa Schiff base macrocycle formed by condensation of three molecules of 2, 6-diformyl-4-methylphenol with three molecules of 2, 6-bis(aminomethyl)-4-methylphenol binds six copper(II) ions in a cyclohexane boat arrangement with two µ2-hydroxo groups (O ⋯ O separation 3.32 Å) occupying the central cavity.Keywords
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