The chemistry of dinitrogen residues. Part 5. [Tris(pyrazolyl)borato]-complexes of titanium(III); the crystal structures of trimethylhydrazinium trichloro[tris(3,5-dimethylpyrazolyl)borato]titanate(III) and dichloro(3,5-dimethylpyrazole)[tris(3,5-dimethylpyrazolyl)borato]titanium(III)
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 1153-1157
- https://doi.org/10.1039/dt9880001153
Abstract
The reaction of trichloro[tris(pyrazolyl)borato]titanium(IV) with hydrazines yields titanium(IV) hydrazido(1–)-species, whereas the corresponding derivative of 3,5-dimethylpyrazole yields titanium(III) compounds which do not contain hydrazine residues. The X-ray crystal structures of two of the latter products, trimethylhydrazinium trichloro[tris(3,5-dimethylpyrazolyl)borato]-titanate(III) and dichloro(3,5-dimethylpyrazole)[tris(3,5-dimethylpyrazolyl)borato]titanium(III), are described.Keywords
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