On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR‘2
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- 23 August 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (37) , 12056-12057
- https://doi.org/10.1021/ja0637494
Abstract
Monophosphine−boranes were shown to behave as bidentate ambiphilic ligands, whose structural versatility has been illustrated by the preparation of PdII and AuI complexes featuring unusual P → M−Cl → B and P → M → B interactions, respectively.Keywords
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