Single-crystal polarized spectrum and paramagnetic anisotropy of five-co-ordinate square pyramidal nickel(II) complexes
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 3269-3283
- https://doi.org/10.1039/j19700003269
Abstract
The single-crystal polarized spectrum of [(Ph2MeAsO)4NiNO3]+NO3 – has been recorded at 300 and 77 K. Principal magnetic susceptibilities of single crystals have been obtained in the temperature range 300–90 K. These properties have been interpreted within a crystal-field framework. Care has been taken not to report a unique ‘ best ’ fit but by the extensive use of mapping procedures to identify regions of fit between the theoretical and experimental quantities.Keywords
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