Enantioselective Palladium Catalyzed Allylic Amination Using New Chiral Pyridine-Phosphine Ligands
- 1 January 1998
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1998 (01) , 49-50
- https://doi.org/10.1055/s-1998-1561
Abstract
Asymmetric palladium catalyzed allylic amination of 5 with various amines has been studied using a new class of chiral pyridine-phosphine ligands. High enantioselectivities of up to 94% ee have been observed using benzylamine, veratrylamine or morpholine as nucleophiles.Keywords
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