Redox chemistry of dichlorophosphorus(V)tetraphenylporphine : isolation and characterization of a stable porphyrin ‘anion’ radical and possible evidence for internal electron transfer
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1279-1280
- https://doi.org/10.1039/c39820001279
Abstract
One-electron reduction of the title complex leads o an extremely stable ring-reduced radical which has been isolated and characterized; addition of a second electron leads to, among other products, the free base tetraphenylporphine via an internal electron transfer.Keywords
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