THE GAS HYDRATE OF BROMOCHLORODIFLUOROMETHANE
- 1 February 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (2) , 208-221
- https://doi.org/10.1139/v60-029
Abstract
An experimental study has been made of the saturation pressure – temperature lines of liquid bromochlorodifluoromethane, liquid bromochlorodiflucromethane – water, bromochlorodifluoromethane hydrate – water, and bromochlorodifluoromethane hydrate – ice systems, for which the characteristic equations are given. Two quadruple points for the hydrate systems have been located and solubilities of water in bromochlorodifluoromethane and bromochlorodifluoromethane in water determined. A systematic treatment of gas hydrate saturation pressure data to yield thermodynamic equations is indicated, and the thermodynamic functions for bromochlorodifluoromethane hydrate and its phase reactions are tabulated. Bromochlorodifluoromethane hydrate is shown to be a stoichiometric compound, and its thermodynamic functions are considered in relation to those of other gas hydrates.Keywords
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