Dalton communications. The first undecaruthenium hydrido carbonyl anion; synthesis and structural characterisation of [Ru11H(CO)27]3?
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 21,p. 3159-3160
- https://doi.org/10.1039/dt9920003159
Abstract
The cluster trianion [Ru11H(CO)27]3– has been obtained from the thermolysis of [Ru3(CO)12] in a methanol–water mixture; an X-ray structure analysis of the [NEt3(CH2Ph)]+ salt shows that the metal core in the anion is a fragment of hexagonal close packing, which may be described alternatively as the condensation between two octahedra and two trigonal bipyramids sharing common triangular faces.Keywords
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