Regiospecific total synthesis of 6-deoxyanthracyclines: 6-deoxycarminomycin
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 530-531
- https://doi.org/10.1039/c39840000530
Abstract
The regiospecific synthesis of the novel anthracycline 6-deoxycarminomycin (14b)is reported: the construction of the aglycone is based on the coupling of 1,4,5-trimethoxy-3-lithionaphthlene(3) to lactone(9) in a regioselective fashion, a new synthetic approach which provides a general route to 6-deoxyanthracyclinones.Keywords
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