Mono- and Bis-(2,2'-bipyridine) and (1,10-phenanthroline) chelates of ruthenium and osaium. III. Mono chelates of bivalent, tervalent, and quadrivalent osmium
- 1 January 1964
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 17 (3) , 315-324
- https://doi.org/10.1071/ch9640315
Abstract
Osmium complexes of the type (BH)[OsX4B], K[OsX4B], [OSX4B]0, [OsX3pyB]0, [OsX3H2OB]0, [OspysB]+/2+, [Ospy4B]2+/3+, [OsX3py3]0, [OsX2py4]0, [OsX2acaB]0, [Osaca2B]0/+, [OsX2glyB]0, [Osgly2B]+, and [OsBen2]2+ have been prepared, where B = 1,10-phenanthroline or 2,2'-bipyridine, py = pyridine, aca = acetylacetonate, gly = glycinate, en = ethylenediamine, and X = Cl or Br. They are generally inert to dissociation of their ligands and to disproportionation. The existence of the possible isomeric forms among the complexes is discussed.Keywords
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