Catalytic Enantioselective Addition of Dimethylzinc to Metallocenecarboxaldehydes and Asymmetric Synthesis of the Catalyst
- 1 October 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (10) , 1050-1052
- https://doi.org/10.1055/s-1995-5185
Abstract
Highly enantioselective addition of dimethylzinc to metallocenecarboxaldehydes catalyzed by chiral 1,2-disubstituted ferrocenyl aminoalcohols was carried out. And the obtained 1-ferrocenylethanol in 98.6% ee was converted into the antipode of the catalyst used.Keywords
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