Metal complexes of thiosemicarbazide: Vibrational analysis of nickel(II) thiosemicarbazide complexes and their deutero isotopomers
- 1 January 1977
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 30 (7) , 1617-1624
- https://doi.org/10.1071/ch9771617
Abstract
The assignments of the in-plane vibrations of the ionic and neutral nickel(II) thiosemicarbazide complexes, Ni(Htsc)2Cl2 and Ni(tsc)2, and their deuterated molecules have been made with the aid of normal coordinate treatments. The out-of-plane vibrations have been assigned empirically. The results of the coordinate treatments have been discussed by referring to the spectra of related molecules. The changes in the infrared bands of thiosemicarbazide on complex formation are also discussed.Keywords
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