Far ultraviolet solution spectroscopy of hydroxide
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Faraday Discussions of the Chemical Society
- Vol. 64, 167-172
- https://doi.org/10.1039/dc9776400167
Abstract
The far ultraviolet solution spectroscopy of hydroxide in a range of both blue and red-shifting solvents shows the absorption to be due to a c.t.t.s. transition. Comparison with the Treinin c.t.t.s. solvent scale shows OH to have a very high solvent sensitivity which, when normalised against the solvent sensitivity of solvated electron, shows a smooth, monotonic relationship for the halides and hydroxide plotted against their ionic radii. A linear correlation between the “excess energy” terms for these ions and their hydration entropies is demonstrated.Keywords
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