X-Ray structures of [Cr2(CO)6(AsMe)9] and [Mo2(CO)6(AsPrn)8]: the stabilisation of an As9 ring and an As8 chain by co-ordination
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 953-954
- https://doi.org/10.1039/c39740000953
Abstract
The compound [Cr2(CO)6(AsMe)9] contains a nine-membered As ring co-ordinated to each Cr atom through three As atoms while [Mo2(CO)6(AsPrn)8] contains a chain of eight As atoms with terminal As atoms bridging both metal atoms and one other arsenic atom in the chain also co-ordinated to each metal, together with an Mo–Mo bond.Keywords
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