Transition-metal catalysed metathesis of phosphorus–phosphorus double bonds
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 2429-2430
- https://doi.org/10.1039/c39950002429
Abstract
W(PMe3)6 is an efficient chloride ion abstracting reagent for the synthesis of RPPR species from RPCl2 precursors; moreover, the W(PMe3)6–RPCl2 solutions catalyse the exchange of the diphosphene PR end-groups via a mechanism closely related to the olefin metathesis process.Keywords
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