Allylic Nitroxyl Spin Label Reagents

Abstract
2,5-Dihydro-3-hydroxymethyl-2,2,5,5-tetramethyl-1H-pyrrol-1-yl-oxy radical is used to prepare new allylic spin labels: thiocyanate, tributylstannane, thiourea, dithiocarbonate, disulfide and diselenide derivatives, with or without allylic rearrangements.

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