Fluorophosphoranes: a new synthesis. Diequatorial four-membered ring in a difluorophosphorane
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 272-273
- https://doi.org/10.1039/c39720000272
Abstract
Reactions of trisubstituted phosphines with bis(trifluoromethyl) peroxide and bis(trifluoromethyl) disulphide proceed rapidly at –78° to give difluorophosphoranes, one of which (II) exists as a slowly equilibrating mixture at low temperatures.Keywords
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