Synthesis of (1α,5α,6α)-6-Amino-3-azabicyclo[3.1.0]hexane, a Novel Achiral Diamine
- 1 November 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (11) , 1097-1099
- https://doi.org/10.1055/s-1996-5684
Abstract
Synthesis of (1α,5α,6α)-6-amino-3-azabicyclo[3.1.0]hexane is described. Ethyl diazoacetate cycloaddition to a pyrroline or maleimide derivative provides the azabicyclohexyl system; amine introduction is then effected using a modified Curtius rearrangement.Keywords
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