Thermal retro-Diels–Alder extrusion of sulphene from a formal sulphene–arene adduct
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 700-701
- https://doi.org/10.1039/c39720000700
Abstract
Dimethyl 2,2-dioxido-4-phenyl-2-thiabicyclo[2,2,2]octa-5,7-diene-5,6-dicarboxylate (3) on heating gives dimethyl biphenyl-2,3-dicarboxylate (2) and sulphene, the latter being detected by trapping experiments.Keywords
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