Trimethylphosphine–tungsten chemistry: hydrido, silyl, fluoro, hydroxy, and aquo derivatives: crystal structure of [W(PMe3)4H2(OH2)F]F
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1400-1402
- https://doi.org/10.1039/c39840001400
Abstract
The compounds W(PMe3)4H2X2(X = H, F, SiH3), [W(PMe3)4H2(OH)2]2+[BF4 –]2, and [W(PMe3)4H2(OH2)F]F, whose crystal structure has been determined, are described; W(PMe3)4(η2-CH2PMe2)H reacts with ethylene giving inter alia W(η-C4H6)2(PMe3)2.Keywords
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