Complexes of 2-Mercaptopyrimidin-4-ol(2-thiouracil) with RhIII, PdII, PdIV, PtII and PtIV

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Abstract
Complexes of 2-mercaptopyrimidin-4-ol with RhIII, PdII, PdIV, PtII and PtIV have been prepared. Their tentative structures have been assigned on the basis of infrared and electronic spectra and magnetic and analytical data. The ligand behaves as a bidentate bridging ligand towards metal ions except for PtII. Crystal field parameters have also been calculated.

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