Intercalation of Water in a Layered Perovskite Compound, NaEuTiO4
- 1 February 1996
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 69 (2) , 349-352
- https://doi.org/10.1246/bcsj.69.349
Abstract
Intercalation of water was observed in a layered perovskite compound, NaEuTiO4, leading to its hydrated derivatives. There are some metastable intermediates in the hydrated derivatives. The hydration process includes several steps that are topotactic. The crystal structure of the hydrated derivatives was identified by Rietveld analysis for the powder X-ray diffraction pattern. It is confirmed that the water molecules are inserted into the sodium layer of NaEuTiO4.This publication has 13 references indexed in Scilit:
- Luminescence properties of layered perovskites activated by Eu3+ ionsJournal of Alloys and Compounds, 1995
- Synthesis, Characterization, and Acid Exchange of the Layered Perovskites: A2Nd2Ti3O10 (A - Na, K)Journal of Solid State Chemistry, 1994
- Ion exchangeable layered niobates as a noble series of photocatalystsResearch on Chemical Intermediates, 1994
- Structure and ionic conductivity of MLaNb2O7 (M K, Na, Li, H)Journal of Alloys and Compounds, 1993
- Structure examination of NaLaNb2O7 synthesized by soft chemistrySolid State Ionics, 1992
- Photocatalytic activity of alkali-metal titanates combined with ruthenium in the decomposition of waterThe Journal of Physical Chemistry, 1991
- A novel series of photocatalysts with an ion-exchangeable layered structure of niobateCatalysis Letters, 1990
- A2Ln2Ti3O10 (A = potassium or rubidium; Ln = lanthanum or rare earth): a new series of layered perovskites exhibiting ion exchangeInorganic Chemistry, 1987
- Photoconduction mechanisms in titanium and rare earth n-type semiconducting electrodes with pyrochlore and perovskite structuresSolid State Communications, 1982
- Crystallographic data of sodium lanthanide titanates (NaLnTiO4)Journal of Inorganic and Nuclear Chemistry, 1968