Lattice of Partly Permanent Dipoles
- 1 August 1957
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 27 (2) , 458-464
- https://doi.org/10.1063/1.1743746
Abstract
The electric susceptibility of a lattice of partly permanent dipoles is determined as a function of the temperature and molecular parameters. The calculation is based on the spherical model approximation. The susceptibility has a discontinuous slope at a critical temperature Tc. Numerical techniques are developed for the evaluation of Tc which may have application elsewhere in the statistical theory of lattices. The theory predicts a critical temperature of 98°K for solid hydrogen bromide which corresponds to a measured value of 89°K.Keywords
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