Comment on: Is multiple quantum nuclear magnetic resonance spectroscopy of liquid water real?
- 15 January 1992
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 96 (2) , 1657-1658
- https://doi.org/10.1063/1.462155
Abstract
Recently, two-dimensional NMR experiments have been performed, which were likely to show that a coupling between otherwise uncoupled or equivalent spins was observable, yielding signals originating from multiple-spin multiple-quantum operators in the density matrix. According to the authors, such surprising results could be interpreted as a consequence of the radiation damping phenomenon. For this purpose, a fully quantum-mechanical frame was used, thus treating the radiation field in a quantized manner. Our analysis, based on the same theoretical grounds, as well as on new experimental arguments, lead us to diverging conclusions.Keywords
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