Sign and magnitude of1K(Sn–C) in trimethylstannyl-lithium: the first example of a negative reduced nuclear spin–spin coupling constant between two directly bound Group IV elements
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 983-984
- https://doi.org/10.1039/c39740000983
Abstract
The electron-mediated reduced nuclear spin–spin coupling constants 1K(Sn–C) and 2K(Sn–H) are negative and positive respectively in trimethylstannyl-lithium; this is attributed to the presence of a lone pair of electorns on the tin atom.Keywords
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